光谱学与光谱分析 |
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Synthesis and Spectral Properties of Novel C60 Derivative/Ag Nanocomposites |
ZHA Qing-qing,WEI Xian-wen* |
College of Chemistry and Materials Science,Anhui Key Laboratory of Functional Molecular Solids,Anhui Normal University,Wuhu 241000, China |
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Abstract The studies on the synthesis and properties of fullerene derivatives had been an active topic in the fullerene chemistry. So synthesis of novel fullerene derivatives and their assembly with functional nanoparticles are very meaningful. In this paper a new bipyridine-substituted [60]fullerene derivative N-methyl-2-[4′-(4″-methyl-2′,2″-bipyridinyl)]-3,4- [60]fulleropyrrolidine (C60BPY) was synthesized by a 1,3-dipolar cycloaddition reaction with C60, 4-methyl-2,2′-bipyridine-4′-carbaldehyde and Sarcosine. Well-fined C60BPY/Ag nanoparticles and nanostructure film were prepared by reduction method using NaBH4 as reagent and self-assembly approach with silver colloid, respectively. Transmission electronic microscope images showed that the diameters of two hybrid structures were about 30-45 nm and 40-55 nm, respectively. The nanoparticles were regular in shape with an uniform size distribution. The results indicated that C60BPY molecule could effectively control the growth and aggregation of silver particles, and make them stable and dispersible well during the process of forming C60BPY/Ag nanocomposites. The UV-Visible absorption spectra showed the surface plasma resonance peaks of silver nanoparticles at 430 and 490 nm in the two nanocomposites, respectively. A red shift of the plasma peak with increasing the size of the nanoparticles was also observed. The fluorescence emission peaks of C60BPY at 720 and 805 nm were significantly quenched by the formation of the C60BPY/Ag nanocomposites. Then the mechanism of quenching was discussed. These nanocomposites may have potential applications in optoelectrionic devices, sensors and catalysis.
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Received: 2007-05-10
Accepted: 2007-08-20
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Corresponding Authors:
WEI Xian-wen
E-mail: xwwei@mail.ahnu.edu.cn
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[1] ZHU Dao-ben (朱道本). Advances in Function Materials(功能材料化学进展). Beijing:Chinese Chemical Industry Press(北京:化学工业出版社),2005. 231. [2] YUAN Wei-en,JIANG Zhi-liang,PAN Hong-cheng,et al(袁伟恩,蒋治良,潘宏程,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005,6:920. [3] YANG Yu-wang,LIU Jing-li(杨玉旺,刘敬利). Industrial Catalysis(工业催化),2003,11(12):7. [4] Liu J,Alvarez J,Ong W,et al. Nano Lett.,2001,1:57. [5] Sudeep P K,Ipe B I,Thomas K G,et al. Nano Lett.,2002,2:29. [6] Du C M,Xu B,Li Y L,et al. New J. Chem.,2001,25:1191. [7] Qu S L,Du C M,Song Y L,et al. Chem. Phys. Lett.,2002,356:403. [8] Gao Y C,Wang Y X,Song Y L,et al. Opt. Commun.,2003,223:103. [9] Maggini M,Scorrano G,Prato M. Journal of American Chemical Society, 1993,115:9798. [10] Prato M,Maggini M,,Accounts of Chem. Res.,1998,31:519. [11] Wei X W,Yao S D,Yin G,et al. Fullerenes Nanotubes and Carbon Nanostructures,2002,10(2):137. [12] Xiang Y,Wei X W,Zhang X M,et al. Inorg. Chem. Commun.,2006,9:452. [13] Xiang Y,Wei X W,Zhang X M,et al. Chinese J. Chem.,2006,24:862. [14] Furue M,Yoshidzumi!T,Kinoshita S,et al. Bull. Chem. Society of Japan,1991,64:1632. [15] Polin J,Schmohel E,Balzani V. Synthesis-Stuttgart,1998,(3):321. [16] Lee P C,Melsel D. J. Phys. Chem.,1982,86:3391. [17] ZHENG Ai-guo,WANG Du-jin,XU Yi-zhuang, et al(郑爱国,王笃金,徐怡庄,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2003,6:1132. [18] MIAO Run-cai,CHEN Guo-fu(苗润才,陈国夫). Acta Photonica Sinica(光子学报),1999,28(6):527. [19] CHEN Guo-zhen,HUANG Xiao-zhi,ZHENG Zhu-zi,et al(陈国珍,黄贤智,郑朱梓,等). Fluorescence Analytical Method(荧光分析法). 2nd ed(第2版). Beijing:Science Press(北京:科学出版社),1990. 109. |
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